Frost resistance - the ability of ceramic tiles to withstand freezing in a humid environment and at temperatures below 0 degrees Celsius. The freezing mechanism is divided into two stages. The first stage is the penetration of water from the environment into the pores of the tile. The second stage is the hardening (freezing) of water inside the pores. As is known, the transition of water from a liquid to a solid state is accompanied by an increase in volume, since the density of ice is less than the density of water. Thus, when water freezes inside the pores, the tile is subjected to mechanical stress, which can lead to cracks or chipping of part of the material.
The frost resistance property of ceramic tiles is not guaranteed in extremely low temperature zones (below -40 °C). This is due to the test conditions of EN ISO 10545-12:1997, as they are carried out at temperatures between +5°C and -5°C. In this regard, manufacturers mark materials suitable for use in such an environment with a special EXTRA°C sign, which in turn indicates testing in the temperature range from -50 °C to +100 °C.
According to EN ISO 10545-12:1997, tests confirming frost resistance properties are not carried out as such. A material is considered frost-resistant if it falls into group 1 of materials according to the degree of water absorption (<3%).
Based on the mechanisms described above, the frost resistance of a material is determined by two parameters: 1) The presence and number of pores that allow water to penetrate into the material; 2) The shape and size of the pores, the volume of voids of which, allows you to distribute the loads of the changing state of water. It follows from this that frost resistance is directly related to water absorption: the lower the water absorption, the greater the likelihood that the material is frost-resistant. However, there are also highly porous materials (with a high rate of water absorption) that are characterized by frost resistance. Frost resistance in this case is due to the shape and size of the pores, allowing moisture to penetrate into the material without destroying it as a result of hydrothermal loads.
Based on the mechanisms described above, the frost resistance of a material is determined by the possibility of water penetration into the material, in other words, the degree of water absorption. Thus, if a material does not absorb water, it is frost-resistant, but if it does, it is not.
According to EN ISO 10545-12:1997, tests confirming frost resistance properties are carried out as follows: ceramic tiles or slabs, after being saturated with water, are subjected to alternate temperatures of +5 ° C and minus 5 ° C. They are then completely frozen for at least 100 freeze-thaw cycles. After 100 freeze/thaw cycles, the faces and edges of ceramic tiles or slabs are examined for damage.
Frost resistance also prevents ice from forming on the face of the tile. This is due to the fact that water, without getting inside the material through the pores of the top layer, seems to “roll off” from the surface.
Material on this issue is presented in the article Frost resistance .
Thermal conductivity is the ability of material bodies to transfer energy (heat exchange) from more heated parts of the body to less heated parts of the body, carried out by chaotically moving particles of the body (atoms, molecules, electrons, etc.). Such heat exchange can occur in any body with a non-uniform temperature distribution, but the mechanism of heat transfer will depend on the state of aggregation of the substance. Porcelain stoneware, due to its dense, almost non-porous structure, is distinguished by relatively high thermal conductivity.
The thermal conductivity of the flooring material becomes particularly important when the choice is made in favor of heated floors (warm screed). Here, naturally, porcelain stoneware with its high thermal conductivity has no competitors.
Porcelain stoneware, due to its dense, almost non-porous structure, has a relatively high thermal conductivity, which is higher than that of some other flooring materials (for example, natural stones such as marble or granite).
The thermal conductivity of ceramic tiles usually varies from 0.5 to 0.9 kcal/(m h °C); lower values apply to porous materials (single and double fired tiles, monoporosity).
The thermal conductivity of ceramic tiles usually varies from 0.5 to 1.1 W/(m °C); lower values apply to porous materials (single and double fired tiles, monoporosity).
The SI unit for thermal conductivity is W/(m K).
The method for determining the thermal conductivity of ceramic tiles is given in ISO 10545-03. The essence of the method is that in steady state, the energy flux density transmitted through thermal conductivity is proportional to the temperature gradient.
Information on this issue is presented in the article Thermal conductivity .
Water absorption is a parameter that determines the porosity of ceramic tiles. It is measured by the amount of water that ceramic tiles absorb under certain laboratory conditions, and is expressed as a percentage of the dry weight of the tiles.
Mark the true statements.
According to EN ISO 10545-3, the penetration of water into the open pores of samples is determined using two methods: boiling and water saturation in a vacuum. When boiling, water saturation occurs only in easily filled open pores; with the vacuum method, almost all open pores are filled.
A low water absorption coefficient indicates that the structure of the tile is porous, and a high coefficient indicates that the structure of the material is more dense.
The lower the degree of water absorption, the more resistant the tile will be to intense mechanical and hydrothermal influences.
According to the EN 14411 standard, ceramic tiles and slabs are divided into three main groups based on water absorption. Where the third group corresponds to the lowest water absorption rates.
According to EN ISO 10545-3, the penetration of water into the open pores of samples is determined exclusively using the water saturation method in a vacuum. The boiling method, as a test that does not allow determining open porosity and bulk density, is considered obsolete.
Material on this issue is presented in the article Water absorption .
Thermal resistance is the ability of ceramic tiles to withstand without damage the stress caused by dimensional deformations due to sudden changes in temperature, especially if such changes are repeated frequently. Which statements do you think are correct?
Thermal resistance is an important physical property of ceramic tiles. Let's imagine, for example, the tiled surface of a kitchen countertop on which a hot pan is placed. The surface of the tile heats up sharply and, as a result, expands, and the lower layers become colder and less expanded as they move away from it. In this state of thermal inhomogeneity, the tile, which does not have the property of heat resistance, could be deformed and, being an inherently rigid material, could crack.
Thermal resistance is the ability of a material to resist the transfer of energy (heat exchange) from more heated parts of the body to less heated bodies, carried out by chaotically moving body particles (atoms, molecules, electrons, etc.).
If we compare the thermal resistance testing methods of the EN ISO 10545-9 standard and GOST 27180-2001, we can conclude that the test requirements of the EN ISO 10545-9 standard are somewhat stricter than the requirements of GOST 27180-2001.
“Resistance to thermal shock” is a property characteristic only of refractory materials, the scope of which is the metallurgical, glass, chemical industries, as well as all other industries where work takes place using blast furnaces, shaft and rotary furnaces.
The test method described in GOST 27180-2001 is as follows: samples are subjected to 10 rapid cycles of temperature changes from 15 °C to 145 °C. The maximum temperature is achieved by placing the samples in an oven for at least 20 minutes, the minimum by completely immersing them in water at a temperature of 15°C. At the end of 10 cycles, samples are inspected for visible defects.
Material on this issue is presented in the article Thermal resistance .
Bending strength is an important mechanical property of ceramic tiles, according to which its quality is controlled. In this case, the resistance of the material is measured in relation to the maximum specific load, with constantly increasing pressure on the surface. Flexural strength is measured in Newtons per square millimeter (N/mm2). In order to fully appreciate the significance of this tile property and correctly apply the test results, you must first check your own understanding of this issue. Please indicate the correct conclusions in your opinion:
In the applied aspect, the tensile strength of the tile, measured in accordance with the standards, is somewhat overestimated relative to the real load-bearing capacity of the tile as part of a multilayer structure, i.e. after installation. This is due to an increase in the area under pressure.
The bending strength is determined by an equation that includes such variables as: breaking force, distance between support rods, width of the tested sample and the smallest thickness of the tested samples along the fracture line.
The tensile strength of the tile, measured in accordance with the standards, in fact, as a rule, is inferior to the real load-bearing capacity of the tile as part of a multilayer structure, i.e. after installation.
Flexural strength is a characteristic that determines the load-bearing capacity of a tile. In addition to the density of the material, it is also affected by the linear dimensions of the tile: length, width and thickness. So, for example, if one tile is twice as thick as another, and they are made of the same material, then its bending strength will be twice as high.
Bending strength is an indicator that does not require additional calculations. It is measured in KG (maximum load leading to destruction of the sample), per surface area (in mm2) to which the force was applied.
Flexural strength is a property of the material, not the tile. This indicator is used to measure the internal cohesive properties of the material that form the tile, rather than to measure a specific mechanical characteristic of the tile itself. In other words, if we take two tiles from the same material, but of different shapes and sizes, for example, one tile is twice as thick as the other, their bending strength will be the same, although the tensile strength will be different. Thus, the characteristics of the tiles differ, despite the fact that they have the same flexural strength.
Material on this issue is presented in the article Flexural strength .
