The surface hardness of ceramic tiles is the ability of the cladding surface to withstand the mechanical stress of other materials. For ceramic facing materials or natural stones, this property is usually indicated in accordance with the mineralogical scale of hardness, the so-called Mohs scale, named after the German mineralogist Friedrich Mohs, who proposed his test method in 1811. Please indicate the correct statements in your opinion.
The Mohs scale (mineralogical hardness scale) is a set of reference minerals for determining relative hardness using the scratching method. 10 minerals, arranged in order of increasing hardness, were taken as standards.
Mohs scale - determined by which of ten standard minerals scratches the material being tested, and which of ten standard minerals scratches the material being tested.
Glazed ceramic tiles are relatively hard, and scratches affect the aesthetic properties of the cladding, while also damaging its functional qualities.
Unglazed ceramic tiles are relatively hard, and scratches only affect the aesthetic properties of the cladding, without damaging its functional qualities.
The Mohs scale is a method of rough comparative assessment of the hardness of materials according to the “harder - softer” system, where the material being tested is scratched by a reference mineral and its surface hardness on the Mohs scale is lower, or it is scratched by a reference mineral and its hardness is higher. Thus, the values of the Mohs scale can be considered indicators of the absolute hardness of minerals.
Material on this issue is presented in the article Surface hardness .
Abrasion resistance is a mechanical characteristic of a lined surface. Indicates the surface’s resistance to wear due to exposure to rubbing objects, surfaces, and materials. Which expressions do you think are correct?
According to the test method EN ISO 10545-7:1998, glazed tiles are divided into wear resistance classes, from "0" to "5". Where fifth class tiles are least resistant to abrasion.
Abrasion resistance is a property characteristic only of glazed ceramic tiles. Since intense and prolonged exposure to the surface over time can lead to partial loss of the glazed layer, and this, in turn, will lead to exposure of the ceramic mass and, as a consequence, to the loss of not only the aesthetic, but also the functional qualities of the facing surface. Damage to unglazed tiles is almost invisible, since abrasion of the top layer leads to exposure of the ceramic mass, which in unglazed tiles is no different from the top layer.
The wear resistance requirements for unglazed ceramic tiles and slabs are set by EN 14411 and depend on water absorption and the method of their manufacture.
Abrasion resistance also affects other functional characteristics of the ceramic tile surface, such as chemical and stain resistance and ease of maintenance. Naturally, this aspect is equally important for glazed and unglazed tiles, because... abrasion leads to a weakening of the tile structure itself, the appearance of pores and microcracks invisible to the naked eye, into which dirt, etc. gets clogged.
The important point is that unlike other quality tests on tiles, durability testing does not determine the value of the tile. The results of the study divide the tiles into classes, each of which corresponds to a specific purpose of the tile, and in no way to divide the tiles into “bad” and “good”.
Information on this issue is presented in the article Abrasion resistance, wear resistance .
Linear thermal expansion is expressed by dimensional changes in any material, including ceramics, due to changes in temperature. Almost all known materials expand as temperature increases and contract as temperature decreases. Moisture expansion refers to the expansion of the tile due to the absorption of moisture. The consequences of such swelling are similar to the expansion of tiles due to an increase in temperature (linear thermal expansion) and are due to the porous structure of the material.
The thermal coefficient of linear expansion α for ceramic tiles is calculated with an accuracy of 0.1•10 -6 °C -1 using the formula: α = dL/(L 0 •dT), where L 0 is the length of the test sample at room temperature; dL is the linear expansion of the test sample during the period of temperature change from room temperature to 100 °C; dT – temperature increase.
A moisture expansion test is required for tiles with a water absorption value greater than 6%.
The recommended upper limit for moisture expansion of ceramic tiles and slabs is 0.06% when testing according to ISO 10545-10 is applied. This means that the upper limit of moisture expansion of ceramic tiles and slabs should not exceed 6 mm/m.
The coefficient of thermal expansion for floor and wall ceramic tiles varies from 4.1•10 -6 °C -1 to 8.1•10 -6 °C -1 . This means that elongation ranges from 40 to 80 thousandths of a millimeter per meter of ceramic tile and per degree rise in temperature.
Methods for determining moisture expansion and temperature coefficient of linear expansion are given in the standards EN ISO 10545-10 and EN ISO 10545-8, respectively.
Material on this issue is presented in the article Linear thermal expansion and moisture expansion .
Thermal resistance is the ability of ceramic tiles to withstand without damage the stress caused by dimensional deformations due to sudden changes in temperature, especially if such changes are repeated frequently. Which statements do you think are correct?
“Resistance to thermal shock” is a property characteristic only of refractory materials, the scope of which is the metallurgical, glass, chemical industries, as well as all other industries where work takes place using blast furnaces, shaft and rotary furnaces.
If we compare the thermal resistance testing methods of the EN ISO 10545-9 standard and GOST 27180-2001, we can conclude that the test requirements of the EN ISO 10545-9 standard are somewhat stricter than the requirements of GOST 27180-2001.
The test method described in GOST 27180-2001 is as follows: samples are subjected to 10 rapid cycles of temperature changes from 15 °C to 145 °C. The maximum temperature is achieved by placing the samples in an oven for at least 20 minutes, the minimum by completely immersing them in water at a temperature of 15°C. At the end of 10 cycles, samples are inspected for visible defects.
Thermal resistance is an important physical property of ceramic tiles. Let's imagine, for example, the tiled surface of a kitchen countertop on which a hot pan is placed. The surface of the tile heats up sharply and, as a result, expands, and the lower layers become colder and less expanded as they move away from it. In this state of thermal inhomogeneity, the tile, which does not have the property of heat resistance, could be deformed and, being an inherently rigid material, could crack.
Thermal resistance is the ability of a material to resist the transfer of energy (heat exchange) from more heated parts of the body to less heated bodies, carried out by chaotically moving body particles (atoms, molecules, electrons, etc.).
Material on this issue is presented in the article Thermal resistance .
Frost resistance - the ability of ceramic tiles to withstand freezing in a humid environment and at temperatures below 0 degrees Celsius. The freezing mechanism is divided into two stages. The first stage is the penetration of water from the environment into the pores of the tile. The second stage is the hardening (freezing) of water inside the pores. As is known, the transition of water from a liquid to a solid state is accompanied by an increase in volume, since the density of ice is less than the density of water. Thus, when water freezes inside the pores, the tile is subjected to mechanical stress, which can lead to cracks or chipping of part of the material.
Frost resistance also prevents ice from forming on the face of the tile. This is due to the fact that water, without getting inside the material through the pores of the top layer, seems to “roll off” from the surface.
Based on the mechanisms described above, the frost resistance of a material is determined by the possibility of water penetration into the material, in other words, the degree of water absorption. Thus, if a material does not absorb water, it is frost-resistant, but if it does, it is not.
Based on the mechanisms described above, the frost resistance of a material is determined by two parameters: 1) The presence and number of pores that allow water to penetrate into the material; 2) The shape and size of the pores, the volume of voids of which, allows you to distribute the loads of the changing state of water. It follows from this that frost resistance is directly related to water absorption: the lower the water absorption, the greater the likelihood that the material is frost-resistant. However, there are also highly porous materials (with a high rate of water absorption) that are characterized by frost resistance. Frost resistance in this case is due to the shape and size of the pores, allowing moisture to penetrate into the material without destroying it as a result of hydrothermal loads.
The frost resistance property of ceramic tiles is not guaranteed in extremely low temperature zones (below -40 °C). This is due to the test conditions of EN ISO 10545-12:1997, as they are carried out at temperatures between +5°C and -5°C. In this regard, manufacturers mark materials suitable for use in such an environment with a special EXTRA°C sign, which in turn indicates testing in the temperature range from -50 °C to +100 °C.
According to EN ISO 10545-12:1997, tests confirming frost resistance properties are carried out as follows: ceramic tiles or slabs, after being saturated with water, are subjected to alternate temperatures of +5 ° C and minus 5 ° C. They are then completely frozen for at least 100 freeze-thaw cycles. After 100 freeze/thaw cycles, the faces and edges of ceramic tiles or slabs are examined for damage.
According to EN ISO 10545-12:1997, tests confirming frost resistance properties are not carried out as such. A material is considered frost-resistant if it falls into group 1 of materials according to the degree of water absorption (<3%).
Material on this issue is presented in the article Frost resistance .
