Thermal conductivity is the ability of material bodies to transfer energy (heat exchange) from more heated parts of the body to less heated parts of the body, carried out by chaotically moving particles of the body (atoms, molecules, electrons, etc.). Such heat exchange can occur in any body with a non-uniform temperature distribution, but the mechanism of heat transfer will depend on the state of aggregation of the substance. Porcelain stoneware, due to its dense, almost non-porous structure, is distinguished by relatively high thermal conductivity.
The thermal conductivity of ceramic tiles usually varies from 0.5 to 0.9 kcal/(m h °C); lower values apply to porous materials (single and double fired tiles, monoporosity).
The method for determining the thermal conductivity of ceramic tiles is given in ISO 10545-03. The essence of the method is that in steady state, the energy flux density transmitted through thermal conductivity is proportional to the temperature gradient.
The thermal conductivity of the flooring material becomes particularly important when the choice is made in favor of heated floors (warm screed). Here, naturally, porcelain stoneware with its high thermal conductivity has no competitors.
The thermal conductivity of ceramic tiles usually varies from 0.5 to 1.1 W/(m °C); lower values apply to porous materials (single and double fired tiles, monoporosity).
The SI unit for thermal conductivity is W/(m K).
Porcelain stoneware, due to its dense, almost non-porous structure, has a relatively high thermal conductivity, which is higher than that of some other flooring materials (for example, natural stones such as marble or granite).
Information on this issue is presented in the article Thermal conductivity .
The surface hardness of ceramic tiles is the ability of the cladding surface to withstand the mechanical stress of other materials. For ceramic facing materials or natural stones, this property is usually indicated in accordance with the mineralogical scale of hardness, the so-called Mohs scale, named after the German mineralogist Friedrich Mohs, who proposed his test method in 1811. Please indicate the correct statements in your opinion.
The Mohs scale is a method of rough comparative assessment of the hardness of materials according to the “harder - softer” system, where the material being tested is scratched by a reference mineral and its surface hardness on the Mohs scale is lower, or it is scratched by a reference mineral and its hardness is higher. Thus, the values of the Mohs scale can be considered indicators of the absolute hardness of minerals.
The Mohs scale (mineralogical hardness scale) is a set of reference minerals for determining relative hardness using the scratching method. 10 minerals, arranged in order of increasing hardness, were taken as standards.
Unglazed ceramic tiles are relatively hard, and scratches only affect the aesthetic properties of the cladding, without damaging its functional qualities.
Glazed ceramic tiles are relatively hard, and scratches affect the aesthetic properties of the cladding, while also damaging its functional qualities.
Mohs scale - determined by which of ten standard minerals scratches the material being tested, and which of ten standard minerals scratches the material being tested.
Material on this issue is presented in the article Surface hardness .
Water absorption is a parameter that determines the porosity of ceramic tiles. It is measured by the amount of water that ceramic tiles absorb under certain laboratory conditions, and is expressed as a percentage of the dry weight of the tiles.
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According to EN ISO 10545-3, the penetration of water into the open pores of samples is determined using two methods: boiling and water saturation in a vacuum. When boiling, water saturation occurs only in easily filled open pores; with the vacuum method, almost all open pores are filled.
According to EN ISO 10545-3, the penetration of water into the open pores of samples is determined exclusively using the water saturation method in a vacuum. The boiling method, as a test that does not allow determining open porosity and bulk density, is considered obsolete.
According to the EN 14411 standard, ceramic tiles and slabs are divided into three main groups based on water absorption. Where the third group corresponds to the lowest water absorption rates.
The lower the degree of water absorption, the more resistant the tile will be to intense mechanical and hydrothermal influences.
A low water absorption coefficient indicates that the structure of the tile is porous, and a high coefficient indicates that the structure of the material is more dense.
Material on this issue is presented in the article Water absorption .
Linear thermal expansion is expressed by dimensional changes in any material, including ceramics, due to changes in temperature. Almost all known materials expand as temperature increases and contract as temperature decreases. Moisture expansion refers to the expansion of the tile due to the absorption of moisture. The consequences of such swelling are similar to the expansion of tiles due to an increase in temperature (linear thermal expansion) and are due to the porous structure of the material.
The coefficient of thermal expansion for floor and wall ceramic tiles varies from 4.1•10 -6 °C -1 to 8.1•10 -6 °C -1 . This means that elongation ranges from 40 to 80 thousandths of a millimeter per meter of ceramic tile and per degree rise in temperature.
Methods for determining moisture expansion and temperature coefficient of linear expansion are given in the standards EN ISO 10545-10 and EN ISO 10545-8, respectively.
The recommended upper limit for moisture expansion of ceramic tiles and slabs is 0.06% when testing according to ISO 10545-10 is applied. This means that the upper limit of moisture expansion of ceramic tiles and slabs should not exceed 6 mm/m.
A moisture expansion test is required for tiles with a water absorption value greater than 6%.
The thermal coefficient of linear expansion α for ceramic tiles is calculated with an accuracy of 0.1•10 -6 °C -1 using the formula: α = dL/(L 0 •dT), where L 0 is the length of the test sample at room temperature; dL is the linear expansion of the test sample during the period of temperature change from room temperature to 100 °C; dT – temperature increase.
Material on this issue is presented in the article Linear thermal expansion and moisture expansion .
The quality and value of the cladding directly depend on the symmetry and uniformity of its individual components, i.e. individual tiles in relation to the quality of the surface and its dimensions. That is why, any dimensional differences and asymmetries of the tiles, deviations of the surface from flatness, which violate the harmony of the cladding and worsen its appearance, will be considered defects. The quality of the surface is determined by the presence of the following defects: gaps, cracks, lack of glaze, unevenness, depressions, pits, damage to the vitrified surface, specks and stains, body defects, decorative defects, darkening, chipped edges and corners.
The method for controlling size and appearance characteristics is described in EN ISO 10545-2. To control the appearance, a minimum of 30 samples of tiles are selected, which must form a surface area of at least 1 m². The appearance of the tiles is checked visually (with the naked eye) at an illumination of 300 lux from a distance of 1 m from the observer’s eyes. According to the standard, preparation of the sample surface and visual assessment of the surface are carried out by different persons. Surface quality is expressed as a percentage of the number of tiles without defects.
If defective tiles do not exceed 5%, then the batch is assigned FIRST GRADE, and if they exceed 5%, then the batch is assigned SECOND GRADE.
The difference in size and dimensional deviations are expressed as a percentage of the working size of the tile.
The following type characteristics are important: length of the sides and thickness, straightness of the sides, orthogonality, flatness of the surface.
The appearance characteristics, as well as the dimensional characteristics, are checked randomly on the tiles before they are packaged. Control is carried out visually by specially trained personnel (MANUAL SORTING) or by machine (AUTOMATIC SORTING).
Information on this issue is presented in the article Dimensional and type characteristics .
