Specifications

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Question 1

The term craquelure itself refers to the crevices and cracks that form on the surface of the glaze. The pattern of these cracks is often circular, although they may be scattered across the surface of the glaze. The reason for the appearance of craquelure is either a difference in the coefficient of thermal expansion of the shard and the glaze, or deformation of the tile due to the impact of mechanical load on it.

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“Late craquelure” occurs under the influence of the external environment during operation. The reasons for its appearance are: thermal shock, insufficient drying of the cement base, excessive cement content in the layer, excessive thickness of the mortar layer.

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The test method for determining the resistance to cracking of glazes (craquelure) of ceramic tiles and slabs is given in the EN ISO 10545-18 standard. To determine the resistance to cracking of glazes, tiles and slabs are subjected to high pressure steam in an autoclave. Then the tiles and slabs, after applying the dye to the glazed surfaces, are examined for the presence of cracks in the glaze.

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Glazed tiles with an "immediate crackle effect" are not considered defective, although manufacturers sometimes deliberately create collections of tiles with a "craquelure effect" for aesthetic purposes.

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This defect can appear immediately after the end of the production cycle (in this case they speak of “immediate craquelure”) or some time after laying the tiles (in this case they speak of “late craquelure”).

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When craquelure appears on polished ceramic tiles and slabs, the term "polished craquelure" is used.

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The material on this issue is presented in the article “ Resistance to craquelure ” and “ Cracking of craquelure glaze ”.

Question 2

Thermal resistance is the ability of ceramic tiles to withstand without damage the stress caused by dimensional deformations due to sudden changes in temperature, especially if such changes are repeated frequently. Which statements do you think are correct?

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The test method described in GOST 27180-2001 is as follows: samples are subjected to 10 rapid cycles of temperature changes from 15 °C to 145 °C. The maximum temperature is achieved by placing the samples in an oven for at least 20 minutes, the minimum by completely immersing them in water at a temperature of 15°C. At the end of 10 cycles, samples are inspected for visible defects.

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Thermal resistance is an important physical property of ceramic tiles. Let's imagine, for example, the tiled surface of a kitchen countertop on which a hot pan is placed. The surface of the tile heats up sharply and, as a result, expands, and the lower layers become colder and less expanded as they move away from it. In this state of thermal inhomogeneity, the tile, which does not have the property of heat resistance, could be deformed and, being an inherently rigid material, could crack.

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If we compare the thermal resistance testing methods of the EN ISO 10545-9 standard and GOST 27180-2001, we can conclude that the test requirements of the EN ISO 10545-9 standard are somewhat stricter than the requirements of GOST 27180-2001.

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“Resistance to thermal shock” is a property characteristic only of refractory materials, the scope of which is the metallurgical, glass, chemical industries, as well as all other industries where work takes place using blast furnaces, shaft and rotary furnaces.

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Thermal resistance is the ability of a material to resist the transfer of energy (heat exchange) from more heated parts of the body to less heated bodies, carried out by chaotically moving body particles (atoms, molecules, electrons, etc.).

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Material on this issue is presented in the article Thermal resistance .

Question 3

The surface hardness of ceramic tiles is the ability of the cladding surface to withstand the mechanical stress of other materials. For ceramic facing materials or natural stones, this property is usually indicated in accordance with the mineralogical scale of hardness, the so-called Mohs scale, named after the German mineralogist Friedrich Mohs, who proposed his test method in 1811. Please indicate the correct statements in your opinion.

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The Mohs scale is a method of rough comparative assessment of the hardness of materials according to the “harder - softer” system, where the material being tested is scratched by a reference mineral and its surface hardness on the Mohs scale is lower, or it is scratched by a reference mineral and its hardness is higher. Thus, the values ​​of the Mohs scale can be considered indicators of the absolute hardness of minerals.

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Glazed ceramic tiles are relatively hard, and scratches affect the aesthetic properties of the cladding, while also damaging its functional qualities.

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Unglazed ceramic tiles are relatively hard, and scratches only affect the aesthetic properties of the cladding, without damaging its functional qualities.

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Mohs scale - determined by which of ten standard minerals scratches the material being tested, and which of ten standard minerals scratches the material being tested.

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The Mohs scale (mineralogical hardness scale) is a set of reference minerals for determining relative hardness using the scratching method. 10 minerals, arranged in order of increasing hardness, were taken as standards.

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Material on this issue is presented in the article Surface hardness .

Question 4

Abrasion resistance is a mechanical characteristic of a lined surface. Indicates the surface’s resistance to wear due to exposure to rubbing objects, surfaces, and materials. Which expressions do you think are correct?

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The wear resistance requirements for unglazed ceramic tiles and slabs are set by EN 14411 and depend on water absorption and the method of their manufacture.

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Abrasion resistance also affects other functional characteristics of the ceramic tile surface, such as chemical and stain resistance and ease of maintenance. Naturally, this aspect is equally important for glazed and unglazed tiles, because... abrasion leads to a weakening of the tile structure itself, the appearance of pores and microcracks invisible to the naked eye, into which dirt, etc. gets clogged.

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According to the test method EN ISO 10545-7:1998, glazed tiles are divided into wear resistance classes, from "0" to "5". Where fifth class tiles are least resistant to abrasion.

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Abrasion resistance is a property characteristic only of glazed ceramic tiles. Since intense and prolonged exposure to the surface over time can lead to partial loss of the glazed layer, and this, in turn, will lead to exposure of the ceramic mass and, as a consequence, to the loss of not only the aesthetic, but also the functional qualities of the facing surface. Damage to unglazed tiles is almost invisible, since abrasion of the top layer leads to exposure of the ceramic mass, which in unglazed tiles is no different from the top layer.

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The important point is that unlike other quality tests on tiles, durability testing does not determine the value of the tile. The results of the study divide the tiles into classes, each of which corresponds to a specific purpose of the tile, and in no way to divide the tiles into “bad” and “good”.

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Information on this issue is presented in the article Abrasion resistance, wear resistance .

Question 5

Water absorption is a parameter that determines the porosity of ceramic tiles. It is measured by the amount of water that ceramic tiles absorb under certain laboratory conditions, and is expressed as a percentage of the dry weight of the tiles.

Mark the true statements.

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According to the EN 14411 standard, ceramic tiles and slabs are divided into three main groups based on water absorption. Where the third group corresponds to the lowest water absorption rates.

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A low water absorption coefficient indicates that the structure of the tile is porous, and a high coefficient indicates that the structure of the material is more dense.

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The lower the degree of water absorption, the more resistant the tile will be to intense mechanical and hydrothermal influences.

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According to EN ISO 10545-3, the penetration of water into the open pores of samples is determined exclusively using the water saturation method in a vacuum. The boiling method, as a test that does not allow determining open porosity and bulk density, is considered obsolete.

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According to EN ISO 10545-3, the penetration of water into the open pores of samples is determined using two methods: boiling and water saturation in a vacuum. When boiling, water saturation occurs only in easily filled open pores; with the vacuum method, almost all open pores are filled.

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Material on this issue is presented in the article Water absorption .

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